Mostrando entradas con la etiqueta Ozone. Mostrar todas las entradas
Mostrando entradas con la etiqueta Ozone. Mostrar todas las entradas

viernes, 18 de julio de 2014

nsf.gov - National Science Foundation - Atmospheric scientists take to the skies to study Colorado Front Range ozone pollution


Results are applicable to metropolitan areas across the country, around the world
The NSF/NCAR C-130 aircraft outside a hangar
The NSF/NCAR C-130 aircraft is based at Rocky Mountain Metropolitan Airport in Broomfield, Colo.
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July 15, 2014
It's July, a hot time in the city of Denver and in urban areas across the United States.
Summertime is also ozone time, a period when ozone pollution peaks. As global temperatures rise with climate change, summertime ozone--an invisible but harmful pollutant--will become more difficult to keep in check, scientists have found.
By 2050, heavily polluted locations in parts of the East, Midwest and West Coast, where ozone already frequently exceeds federally recommended levels, could face unhealthy summer air in most years.
How and where does summertime ozone begin?
 
Tracking the origins of summertime ozone
This month, scientists at the National Center for Atmospheric Research (NCAR), University of Colorado Boulder and other organizations are launching a field project across the northern Front Range of Colorado to track the origins of summertime ozone.
The researchers will use specially-equipped aircraft, mobile radars, balloon-mounted sensors and sophisticated computer simulations to measure local and far-flung air pollution sources.
Results from the study will provide needed information to officials working to ensure that air in the region is healthy to breathe.
Reasons summertime ozone pollution on the northern Front Range often exceeds standards include:
  • Man-made emissions from human activities such as transportation, energy generation, oil and gas activities and agriculture;
  • Natural emissions from vegetation and wildfires;
  • Long-range transport of pollution from other western states or cross-continental transport from Asia;
  • Downward transport of air from the stratosphere.
The scientists will investigate how these sources, along with unique meteorology and air flow patterns in the region, contribute to ground level ozone.
Ground-level ozone isn't directly emitted. It's formed by the reaction of hydrocarbons and carbon monoxide in the presence of nitrogen oxides and sunlight: ozone precursors.
"Our goal is to produce an accurate and detailed view of all the diverse sources of ozone pollution along the Front Range," says NCAR scientist Gabriele Pfister, a lead scientist on the project.
"We want to fingerprint where the pollution comes from and analyze what happens when it mixes in the atmosphere."
 
Ozone: From human activities, natural sources
 
Known as the Front Range Air Pollution and Photochemistry Experiment (FRAPPÉ), the study will focus on the urban corridor from south of Denver north to Fort Collins as well as the adjacent plains and mountains.
Scientists also want to determine how much pollution comes from upwind areas, including other states and countries.
Funded through a federal-state partnership, FRAPPÉ is supported by the Colorado Department of Public Health and Environment and the National Science Foundation (NSF), NCAR's sponsor.
"FRAPPÉ will provide a detailed look at the sources of pollution that affect the air quality of the Colorado Front Range and the health of both people and ecosystems," says Linnea Avallone, a program director in NSF's Division of Atmospheric and Geospace Sciences.
"The data gathered will be used to better understand the unique combination of chemistry and meteorology that leads to poor air quality and will help in developing solutions to the problem."
 
Two major projects converge
 
To provide additional detail across the region, scientists will closely coordinate FRAPPÉ with a second air quality mission taking place on the Front Range at the same time.
DISCOVER-AQ (Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality) is a study led by NASA to improve the ability of satellites to assess air quality.
DISCOVER-AQ flights and ground observations will focus on the northern Front Range, while FRAPPÉ will gather measurements from the surrounding region.
In all, some 200 scientists, technicians and pilots from around the country will converge on the Front Range for the combined projects.
The researchers will quantify emissions from industrial facilities, power plants, motor vehicles, agricultural operations, oil and gas drilling, fires and other sources.
They also will measure naturally-occurring emissions from trees and other plants that combine with emissions generated by human activities to form ozone and other pollutants.
 
Developing a 3-D picture
 
Colorado, like other states, relies on a limited number of ground-based stations to monitor air quality and help guide statewide policies and permitting.
But a full, three-dimensional picture of the processes that affect air quality, including conditions far upwind and high up in the atmosphere, requires a three-pronged approach with measurements from aircraft, satellites and the ground.
"By bringing together aircraft, satellites and ground-based instruments, we can analyze the amounts and types of pollutants that are emitted in the Front Range as well as [those] transported from other places, how they evolve and how air circulation patterns near the mountains move them around," says NCAR scientist Frank Flocke, a lead scientist on FRAPPÉ.
During the projects, which run from July 16 through mid-August, Front Range residents may notice occasional low-flying research aircraft taking measurements of the atmosphere.
The aircraft will spiral down at times, taking samples of air as they fly directly above ground instruments that measure air at the surface and observe the atmosphere above.
The data gathered by the projects will go through a quality assurance process, then become publicly available in about six months. Scientists will use the data to begin publishing research results in about a year.
 
An armada of instruments
 
FRAPPÉ and DISCOVER AQ will use similar payloads for their aircraft. The teams will conduct wingtip-to-wingtip intercomparison flights several times during the project, sampling air in the same places to make sure the instrument readings are comparable.
A network of instruments on towers, rooftops and other sites will continuously monitor ozone and the gases that react to form it.
Other activities, such as measurements from tethered balloons and from laser-based radars, will be closely coordinated with the flights.
The researchers will draw on forecasts and nowcasts of both weather and air quality from a large number of computer models to assess daily conditions and make final decisions on when to fly and where to gather atmospheric samples.
"FRAPPÉ is a major collaborative study that will produce the most complete picture ever of summertime air pollution on the Front Range," says Thomas Bogdan, president of the University Corporation for Atmospheric Research, which manages NCAR.
"This effort will dramatically advance our understanding of air quality and its potential effects. The results have the potential to help not only people living on Colorado's Front Range, but residents of other metropolitan areas with similar conditions."
In addition to NCAR, the University of Colorado Boulder and the Colorado Department of Public Health and Environment, the FRAPPÉ team includes scientists from the National Oceanic and Atmospheric Administration; National Park Service; Regional Air Quality Council; Global Ozone Project; Western Regional Air Partnership; Environmental Protection Agency; Colorado State University; Cooperative Institute for Research in the Environmental Sciences; University of California, Berkeley; University of Wisconsin; University of Cincinnati; George Institute of Technology; University of California, Riverside; Aerodyne Inc.; U.S. Naval Academy; University of Rhode Island; University of California, Irvine and Princeton University.
-- Cheryl Dybas, NSF (703) 292-7734 cdybas@nsf.gov
-- David Hosansky, NCAR (303) 497-8611 hosansky@ucar.edu
Related Programs Atmospheric Chemistry
Related WebsitesNSF News: Climate change may worsen summertime ozone pollution:
 http://www.nsf.gov/news/news_summ.jsp?cntn_id=131307
NSF Grant: RAPID: Measurements of Hydroxyl Radicals, Sulfuric Acid, sCIs, Hydroperoxy Radicals and Organic Peroxy Radicals on the C-130 during FRAPPE:
 
map showing the state of Colorado and the FRAPPE study area
FRAPPÉ scientists will study atmospheric conditions across the Colorado Front Range.
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woman working in a facility to  mount air-sampling instruments on airplane
The NSF/NCAR C-130 aircraft includes pods on each wing where air-sampling instruments are mounted.
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Scientists working on a data analysis console
Scientists work on a data analysis console that will fly aboard the aircraft during FRAPPÉ.
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Graphic showing how ground level ozone forms
How does ground level ozone form? Through complex chemistry from atmosphere to city street.
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graphic with text If you breathe the air, this alert is for you
If you breathe the air, this alert is for you: Ozone levels affect all of us.
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the National Science Foundation(NSF),
Guillermo Gonzalo Sánchez Achutegui

domingo, 28 de octubre de 2012

NASA - 2012 Antarctic Ozone Hole Second Smallest in 20 Years

 
 False-color view of total ozone over the Antarctic pole. The purple and blue colors are where there is the least ozone, and the yellows and reds are where there is more ozone.

October 2012 (All images)
 October Climatology (All images)
 http://ozonewatch.gsfc.nasa.gov/

Ozone facts

What is ozone?

Ozone is a colorless gas. Chemically, ozone is very active; it reacts readily with a great many other substances. Near the Earth’s surface, those reactions cause rubber to crack, hurt plant life, and damage people’s lung tissues. But ozone also absorbs harmful components of sunlight, known as “ultraviolet B”, or “UV-B”. High above the surface, above even the weather systems, a tenuous layer of ozone gas absorbs UV-B, protecting living things below.

What is a Dobson Unit?

The Dobson Unit (DU) is the unit of measure for total ozone. If you were to take all the ozone in a column of air stretching from the surface of the earth to space, and bring all that ozone to standard temperature (0 °Celsius) and pressure (1013.25 millibars, or one atmosphere, or “atm”), the column would be about 0.3 centimeters thick. Thus, the total ozone would be 0.3 atm-cm. To make the units easier to work with, the “Dobson Unit” is defined to be 0.001 atm-cm. Our 0.3 atm-cm would be 300 DU.

What is the ozone hole?

Each year for the past few decades during the Southern Hemisphere spring, chemical reactions involving chlorine and bromine cause ozone in the southern polar region to be destroyed rapidly and severely. This depleted region is known as the “ozone hole”.
The area of the ozone hole is determined from a map of total column ozone. It is calculated from the area on the Earth that is enclosed by a line with a constant value of 220 Dobson Units. The value of 220 Dobson Units is chosen since total ozone values of less than 220 Dobson Units were not found in the historic observations over Antarctica prior to 1979. Also, from direct measurements over Antarctica, a column ozone level of less than 220 Dobson Units is a result of the ozone loss from chlorine and bromine compounds. 

2012 Antarctic Ozone Hole Second Smallest in 20 Years
 
 
WASHINGTON -- The average area covered by the Antarctic ozone hole this year was the second smallest in the last 20 years, according to data from NASA and National Oceanic and Atmospheric Administration (NOAA) satellites. Scientists attribute the change to warmer temperatures in the Antarctic lower stratosphere.

The ozone hole reached its maximum size Sept. 22, covering 8.2 million square miles (21.2 million square kilometers), or the area of the United States, Canada and Mexico combined. The average size of the 2012 ozone hole was 6.9 million square miles (17.9 million square kilometers). The Sept. 6, 2000 ozone hole was the largest on record at 11.5 million square miles (29.9 million square kilometers).

"The ozone hole mainly is caused by chlorine from human-produced chemicals, and these chlorine levels are still sizable in the Antarctic stratosphere," said NASA atmospheric scientist Paul Newman of NASA's Goddard Space Flight Center in Greenbelt, Md. "Natural fluctuations in weather patterns resulted in warmer stratospheric temperatures this year. These temperatures led to a smaller ozone hole."

The ozone layer acts as Earth's natural shield against ultraviolet radiation, which can cause skin cancer. The ozone hole phenomenon began making a yearly appearance in the early 1980s. The Antarctic ozone layer likely will not return to its early 1980s state until about 2065, Newman said. The lengthy recovery is because of the long lifetimes of ozone-depleting substances in the atmosphere. Overall atmospheric ozone no longer is declining as concentrations of ozone-depleting substances decrease. The decrease is the result of an international agreement regulating the production of certain chemicals.

This year also showed a change in the concentration of ozone over the Antarctic. The minimum value of total ozone in the ozone hole was the second highest level in two decades. Total ozone, measured in Dobson units (DU), reached 124 DU on Oct. 1. NOAA ground-based measurements at the South Pole recorded 136 DU on Oct. 5. When the ozone hole is not present, total ozone typically ranges from 240-500 DU.

This is the first year growth of the ozone hole has been observed by an ozone-monitoring instrument on the Suomi National Polar-orbiting Partnership (NPP) satellite. The instrument, called the Ozone Mapping Profiler Suite (OMPS), is based on previous instruments, such as the Total Ozone Mapping Spectrometer (TOMS) and the Solar Backscatter Ultraviolet instrument (SBUV/2), which have flown on multiple satellites. OMPS continues a satellite record dating back to the early 1970s.

In addition to observing the annual formation and extent of the ozone hole, scientists hope OMPS will help them better understand ozone destruction in the middle and upper stratosphere with its Nadir Profiler. Ozone variations in the lower stratosphere will be measured with its Limb Profiler.

"OMPS Limb looks sideways, and it can measure ozone as a function of height," said Pawan K. Bhartia, a NASA atmospheric physicist and OMPS Limb instrument lead. "This OMPS instrument allows us to more closely see the vertical development of Antarctic ozone depletion in the lower stratosphere where the ozone hole occurs."

NASA and NOAA have been monitoring the ozone layer on the ground and with a variety of instruments on satellites and balloons since the 1970s. Long-term ozone monitoring instruments have included TOMS, SBUV/2, Stratospheric Aerosol and Gas Experiment series of instruments, the Microwave Limb Sounder, the Ozone Monitoring Instrument, and the OMPS instrument on Suomi NPP. Suomi NPP is a bridging mission leading to the next-generation polar-orbiting environmental satellites called the Joint Polar Satellite System, which will extend ozone monitoring into the 2030s.

NASA and NOAA have a mandate under the Clean Air Act to monitor ozone-depleting gases and stratospheric depletion of ozone. NOAA complies with this mandate by monitoring ozone via ground and satellite measurements. The NOAA Earth System Research Laboratory in Boulder, Colo., performs the ground-based monitoring. The Climate Prediction Center performs the satellite monitoring.

To monitor the state of the ozone layer above Antarctica, visit:
 NASA
Guillermo GOnzalo Sánchez Achutegui
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